Search results for "perovskite stability"

showing 2 items of 2 documents

Preferred Growth Direction by PbS Nanoplatelets Preserves Perovskite Infrared Light Harvesting for Stable, Reproducible, and Efficient Solar Cells

2020

Formamidinium-based perovskite solar cells (PSCs) present the maximum theoretical efficiency of the lead perovskite family. However, formamidinium perovskite exhibits significant degradation in air. The surface chemistry of PbS has been used to improve the formamidinium black phase stability. Here, the use of PbS nanoplatelets with (100) preferential crystal orientation is reported, to potentiate the repercussion on the crystal growth of perovskite grains and to improve the stability of the material and consequently of the solar cells. As a result, a vertical growth of perovskite grains, a stable current density of 23 mA cm(-2), and a stable incident photon to current efficiency in the infr…

Materials sciencePbS nanoplateletsInfraredperovskitesCrystal growth02 engineering and technology010402 general chemistryHIGHLY EFFICIENT01 natural sciencesperovskite stabilityPlanarMetastabilityGeneral Materials ScienceformamidiniumreproducibilityPerovskite (structure)Renewable Energy Sustainability and the Environmentbusiness.industryLATERAL SIZE CONTROLNANOSHEETS021001 nanoscience & nanotechnology0104 chemical sciencesChemistryFormamidiniumPhysics and AstronomyOptoelectronicsDegradation (geology)0210 nano-technologybusinessCurrent densityMICROMETER
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Degradation mechanisms in organic lead halide perovskite light-emitting diodes

2019

Organic–inorganic metal halide perovskites have attracted significant attention for low-cost, high-efficiency, color-pure light-emitting applications. However, as seen in many reports so-far, perovskite light-emitting diodes (PeLED) suffer from poor operational lifetime, limiting their practical use. The underlying degradation mechanism is a topic of crucial importance. Here, the degradation mechanisms of methylammonium lead bromide based PeLED are investigated. When the PeLED is electrically biased, there is an initial raise in the luminance followed by a rapid reduction in luminance and current density. Microscopic studies reveal the formation of micrometer-sized spots that are photolumin…

Materials sciencePhotoluminescenceHalide02 engineering and technologyElectroluminescencedevice lifetime010402 general chemistry01 natural sciencesperovskite stabilitylaw.inventionlawMaterialsPerovskite (structure)Diodedegradationbusiness.industrymetal halide perovskites021001 nanoscience & nanotechnologylight emitting diodesAtomic and Molecular Physics and OpticsCathode0104 chemical sciencesElectronic Optical and Magnetic MaterialsDegradation (geology)Optoelectronics0210 nano-technologybusinessLight-emitting diode
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